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By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,

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Additional info for 5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010

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Pietro VINCENZINI, Kunihito KOUMOTO, Nicola ROMEO and Mark MEHOS 25 Summary We have prepared cobalt-substituted HMS samples in order to supply much electron carriers based on the valence electron count (VEC) concept. 10 for the (Mn1-xCox)Si solid solution. The observed change in lattice parameters is almost identical to that of the Fe-substituted samples, indicating that the electron carriers are effectively introduced as in the case of the Fe-system. 06(1). However, all the samples are found to be p-type.

An important question is the positions of the Sr and Eu guest atoms in Ba8-xAxGa16Si30 (A=Sr, Eu; x=1, 2). The Rietveld structure refinements confirmed that the Sr and Eu guest atoms preferentially occupy the 28 5th FORUM ON NEW MATERIALS PART C 2a site in the smaller cage but the occupancy of Sr atoms on the 6d site is relatively large in comparison to Eu atoms. The similar trend was reported for Ba6Eu2Cu4Si42 [5] and EuxBa8-xAl14Si31 [8]. The structure refinements also show that the atomic displacement parameters ADPs on the 2a site for Ba8-xEuxGa16Si30 (x=1 and 2) are significantly increased by a factor more than two relative to Ba8Ga16Si30.

C. L. Condron, S. M. Kauzlarich, and G. S. Nolas: Inorg. , 46 (2007) 2556-2562. X. Tang, P. Li, S. Deng, and Q. Zhang: J. Appl. , 104 (2008) 013706. K. Koga, K. Suzuki, M. Fukamoto, H. Anno, T. Tanaka, and S. Yamamoto: J. Electron. , 38 (2009) 1427-1432. K. Akai, G. Zhao, K. Koga, K. Oshiro and M. Matsuura: IEEE Proc. 24th Int. Conf. 215-218. K. Koga, H. Anno, K. Akai, M. Matsuura, and K. Matsubara: Mater. , 48 (2007) 2108-2113. F. Izumi and T. Ikeda: Mater. Sci. Forum, 321-324 (2000) 198. B. C.

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5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010 by Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,


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