By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,
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Additional info for 5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010
Pietro VINCENZINI, Kunihito KOUMOTO, Nicola ROMEO and Mark MEHOS 25 Summary We have prepared cobalt-substituted HMS samples in order to supply much electron carriers based on the valence electron count (VEC) concept. 10 for the (Mn1-xCox)Si solid solution. The observed change in lattice parameters is almost identical to that of the Fe-substituted samples, indicating that the electron carriers are effectively introduced as in the case of the Fe-system. 06(1). However, all the samples are found to be p-type.
An important question is the positions of the Sr and Eu guest atoms in Ba8-xAxGa16Si30 (A=Sr, Eu; x=1, 2). The Rietveld structure refinements confirmed that the Sr and Eu guest atoms preferentially occupy the 28 5th FORUM ON NEW MATERIALS PART C 2a site in the smaller cage but the occupancy of Sr atoms on the 6d site is relatively large in comparison to Eu atoms. The similar trend was reported for Ba6Eu2Cu4Si42  and EuxBa8-xAl14Si31 . The structure refinements also show that the atomic displacement parameters ADPs on the 2a site for Ba8-xEuxGa16Si30 (x=1 and 2) are significantly increased by a factor more than two relative to Ba8Ga16Si30.
C. L. Condron, S. M. Kauzlarich, and G. S. Nolas: Inorg. , 46 (2007) 2556-2562. X. Tang, P. Li, S. Deng, and Q. Zhang: J. Appl. , 104 (2008) 013706. K. Koga, K. Suzuki, M. Fukamoto, H. Anno, T. Tanaka, and S. Yamamoto: J. Electron. , 38 (2009) 1427-1432. K. Akai, G. Zhao, K. Koga, K. Oshiro and M. Matsuura: IEEE Proc. 24th Int. Conf. 215-218. K. Koga, H. Anno, K. Akai, M. Matsuura, and K. Matsubara: Mater. , 48 (2007) 2108-2113. F. Izumi and T. Ikeda: Mater. Sci. Forum, 321-324 (2000) 198. B. C.
5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010 by Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,